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Beilstein J. Org. Chem. 2013, 9, 655–663, doi:10.3762/bjoc.9.74
Graphical Abstract
Scheme 1: Structure of ryanodine and the Diels–Alder reactions for construction of the potential intermediate...
Scheme 2: Asymmetric synthesis of 7 and determination of the absolute configuration at C4 of 15 by the modifi...
Scheme 3: Generation of 17 through the 6π-electrocyclic reaction and the Diels–Alder reaction.
Scheme 4: Rationale of the stereoselectivity of the Diels–Alder reaction.
Scheme 5: Synthesis of C2-symmetric 1.